Key: Win : Draw : Loss
| Date | Home | Away | Ref | ||
|---|---|---|---|---|---|
| 03/08/2013 | Southend | 1 | 0 | Plymouth | R Lewis |
| 10/08/2013 | Plymouth | 0 | 2 | Fleetwood Town | C Sarginson |
| 17/08/2013 | Cheltenham | 1 | 3 | Plymouth | C Breakspear |
| 24/08/2013 | Plymouth | 1 | 0 | Rochdale | B Malone |
| 31/08/2013 | Morecambe | 2 | 1 | Plymouth | T Harrington |
| 07/09/2013 | Plymouth | 1 | 0 | Bristol Rvs | A Davies |
| 14/09/2013 | Plymouth | 0 | 3 | Wycombe | S Hooper |
| 21/09/2013 | Scunthorpe | 1 | 0 | Plymouth | G Scott |
| 28/09/2013 | Plymouth | 0 | 0 | Accrington | F Graham |
| 05/10/2013 | Exeter | 3 | 1 | Plymouth | A Marriner |
| 12/10/2013 | Plymouth | 1 | 1 | Portsmouth | S Martin |
| 19/10/2013 | Hartlepool | 1 | 0 | Plymouth | S Mathieson |
| 22/10/2013 | Plymouth | 0 | 0 | Newport County | O Langford |
| 26/10/2013 | Mansfield | 0 | 1 | Plymouth | G Sutton |
| 02/11/2013 | Plymouth | 1 | 0 | Northampton | T Kettle |
| 16/11/2013 | York | 1 | 1 | Plymouth | S Stockbridge |
| 23/11/2013 | Plymouth | 2 | 1 | Dag and Red | S Rushton |
| 26/11/2013 | Torquay | 1 | 1 | Plymouth | R East |
| 30/11/2013 | Plymouth | 0 | 1 | Burton | G Salisbury |
| 14/12/2013 | Chesterfield | 2 | 0 | Plymouth | A Haines |
| 21/12/2013 | Plymouth | 2 | 1 | Bury | M Bull |
| 26/12/2013 | Oxford | 2 | 3 | Plymouth | A Davies |
| 29/12/2013 | AFC Wimbledon | 1 | 1 | Plymouth | A Woolmer |
| 01/01/2014 | Plymouth | 2 | 0 | Torquay | K Stroud |
| 11/01/2014 | Plymouth | 1 | 1 | Southend | T Robinson |
| 18/01/2014 | Rochdale | 3 | 0 | Plymouth | M Brown |
| 25/01/2014 | Plymouth | 1 | 1 | Cheltenham | L Collins |
| 01/02/2014 | Plymouth | 1 | 1 | Mansfield | P Bankes |
| 08/02/2014 | Northampton | 0 | 2 | Plymouth | N Miller |
| 15/02/2014 | Plymouth | 0 | 4 | York | C Breakspear |
| 22/02/2014 | Dag and Red | 1 | 2 | Plymouth | M Naylor |
| 25/02/2014 | Fleetwood Town | 0 | 4 | Plymouth | S Bratt |
| 01/03/2014 | Plymouth | 5 | 0 | Morecambe | G Horwood |
| 08/03/2014 | Bristol Rvs | 2 | 1 | Plymouth | J Linington |
| 11/03/2014 | Wycombe | 0 | 1 | Plymouth | A Davies |
| 15/03/2014 | Plymouth | 0 | 2 | Scunthorpe | D Drysdale |
| 18/03/2014 | Plymouth | 2 | 1 | Chesterfield | O Langford |
| 22/03/2014 | Accrington | 1 | 1 | Plymouth | T Kettle |
| 25/03/2014 | Plymouth | 1 | 2 | Exeter | R Madley |
| 05/04/2014 | Burton | 1 | 0 | Plymouth | M Haywood |
| 08/04/2014 | Newport County | 1 | 2 | Plymouth | S Mathieson |
| 12/04/2014 | Plymouth | 0 | 2 | Oxford | M Russell |
| 18/04/2014 | Bury | 4 | 0 | Plymouth | E Ilderton |
| 21/04/2014 | Plymouth | 1 | 2 | AFC Wimbledon | K Hill |
| 26/04/2014 | Plymouth | 1 | 1 | Hartlepool | G Sutton |
| 03/05/2014 | Portsmouth | 3 | 3 | Plymouth | S Attwell |