Key: Win : Draw : Loss
| Date | Home | Away | Ref | ||
|---|---|---|---|---|---|
| 03/08/2013 | Bournemouth | 2 | 1 | Charlton | A D'Urso |
| 10/08/2013 | Charlton | 0 | 1 | Middlesbrough | P Tierney |
| 17/08/2013 | Barnsley | 2 | 2 | Charlton | J Simpson |
| 31/08/2013 | Charlton | 2 | 1 | Leicester | D Deadman |
| 14/09/2013 | Watford | 1 | 1 | Charlton | K Woolmer |
| 17/09/2013 | Huddersfield | 2 | 1 | Charlton | S Attwell |
| 21/09/2013 | Charlton | 0 | 1 | Millwall | A D'Urso |
| 28/09/2013 | Burnley | 3 | 0 | Charlton | D Coote |
| 01/10/2013 | Charlton | 1 | 1 | Nott'm Forest | F Graham |
| 05/10/2013 | Charlton | 0 | 0 | Blackpool | K Hill |
| 19/10/2013 | Blackburn | 0 | 1 | Charlton | K Wright |
| 27/10/2013 | Charlton | 0 | 0 | Wigan | S Martin |
| 02/11/2013 | Birmingham | 0 | 1 | Charlton | S Mathieson |
| 09/11/2013 | Charlton | 2 | 4 | Leeds | K Stroud |
| 23/11/2013 | QPR | 1 | 0 | Charlton | D Whitestone |
| 26/11/2013 | Charlton | 2 | 0 | Doncaster | L Collins |
| 30/11/2013 | Charlton | 0 | 1 | Ipswich | S Duncan |
| 03/12/2013 | Reading | 1 | 0 | Charlton | D Sheldrake |
| 07/12/2013 | Yeovil | 2 | 2 | Charlton | C Pawson |
| 14/12/2013 | Charlton | 0 | 2 | Derby | A Davies |
| 21/12/2013 | Bolton | 1 | 1 | Charlton | P Gibbs |
| 26/12/2013 | Charlton | 3 | 2 | Brighton | M Russell |
| 29/12/2013 | Charlton | 1 | 1 | Sheffield Weds | F Graham |
| 01/01/2014 | Ipswich | 1 | 1 | Charlton | S Attwell |
| 18/01/2014 | Middlesbrough | 1 | 0 | Charlton | K Stroud |
| 28/01/2014 | Doncaster | 3 | 0 | Charlton | P Tierney |
| 01/02/2014 | Wigan | 2 | 1 | Charlton | M Bull |
| 08/02/2014 | Charlton | 0 | 2 | Birmingham | J Adcock |
| 22/02/2014 | Charlton | 1 | 0 | QPR | E Ilderton |
| 01/03/2014 | Leicester | 3 | 0 | Charlton | J Simpson |
| 12/03/2014 | Charlton | 0 | 0 | Huddersfield | B Malone |
| 15/03/2014 | Millwall | 0 | 0 | Charlton | P Dowd |
| 18/03/2014 | Charlton | 1 | 0 | Bournemouth | J Linington |
| 22/03/2014 | Charlton | 0 | 3 | Burnley | O Langford |
| 25/03/2014 | Nott'm Forest | 0 | 1 | Charlton | A Haines |
| 29/03/2014 | Derby | 3 | 0 | Charlton | M Haywood |
| 01/04/2014 | Leeds | 0 | 1 | Charlton | S Duncan |
| 05/04/2014 | Charlton | 0 | 1 | Reading | A Madley |
| 08/04/2014 | Charlton | 3 | 2 | Yeovil | G Scott |
| 12/04/2014 | Brighton | 3 | 0 | Charlton | R East |
| 15/04/2014 | Charlton | 1 | 2 | Barnsley | I Williamson |
| 18/04/2014 | Charlton | 0 | 0 | Bolton | B Malone |
| 21/04/2014 | Sheffield Weds | 2 | 3 | Charlton | T Harrington |
| 26/04/2014 | Charlton | 1 | 3 | Blackburn | M Naylor |
| 29/04/2014 | Charlton | 3 | 1 | Watford | D Bond |
| 03/05/2014 | Blackpool | 0 | 3 | Charlton | K Friend |